By Jaroslav Heyrovský
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C(j)mmuns 79, 433 (1954). WEAVER J. , PARRY R . W . : J. Chem. Soc. 76, 6258 (1954); 78, 5542 (1956). : Chem. listy 49, 485 (1955); Collection Czechoslov. Chem. Communs 20, 1125 (1955). : Chem. listy 57,1274 (1957); Collection Czechoslov. Chem. Communs 23, 383 (1958). 52. NERNST W . , GLASER L . : Z . Elektrochem. 4, 355, 373, 397 (1898). 53. KRYUKOVA T . , SINYAKOVA S . , AREFYEVA T . , p. 120. Goskhimizdat. Moscow 1959. 54. : Collection Czechoslov. Chem. Communs 28, 2874 (1963). 55. TRIEBEL H .
M . , LINGANE J. : Polarography I. part, p. 7 9 , Interscience, New York 1 9 5 2 . e. 2 , p. 8 4 . KoLTHOFF 4 . K o L T H O F F I. M . , LINGANE J. : Chem. Rev. 24, 1 ( 1 9 3 9 ) . 5. LINGANE J. : Ind. Eng. , Anal. Ed. 7 4 , 6 5 5 ( 1 9 4 2 ) . 6. LINGANE J. : Ind. Eng. , Anal. Ed. 16, 3 2 9 ( 1 9 4 4 ) . 7. FURNESS W . : Analyst 7(5, 1 7 8 ( 1 9 5 1 ) . 8. VLCEK A. Α . : Chem. listy 4 7 , 1 4 4 0 ( 1 9 5 3 ) . 9. SMITH G . : Trans. Faraday Soc. 4 7 , 6 3 ( 1 9 5 1 ) . 10. M A C NEVIN W . M . , BALIS E .
The electrical field created by this voltage drop causes a motion of the ions, which is termed migration. If the direction of migration agrees with the direction of diffusion the resulting limiting current exceeds the diffusion current [ 1 ] . If the direction of migration is opposite to that for diffusion a decrease in the limiting current may be observed. The voltage drop iR and thus the migration 5—Principles of Polarography Literature p. 72 66 V. Migration Currents current of the ions may be decreased by adding an excess of an indifferent electrolyte.
Principles of Polarography by Jaroslav Heyrovský