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Download e-book for iPad: Layered double hydroxides by ed.Vicente Rives.

By ed.Vicente Rives.

ISBN-10: 1590330609

ISBN-13: 9781590330609

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The behaviour of [Cu-Cr-SO4] is quite different at temperatures lower than 80°C, where the initial basal spacing is retained. The contraction process is completed at 100 °C, leading to a grafted phase with an interlamellar distance quite similar to that of [Cu-Cr-Cr2O7]. -Schematic view of LDH phases grafted with XO42-, and X2O72- oxoanions. Reprinted from C. Forano, A. De Roy, D. Depège, M. Khaldi, F. Z. El Métoui and J. P. Besse, Post-synthesis modification of layered double hydroxides, in Synthesis of Porous Materials.

Smith and E. Oldfeild, Am. Miner. 70 (1985) 537. J. M. Serratosa, J. Am. Chem. Soc. 106 (1984) 4790. S. Bonnet, C. Forano, A. de Roy, P. Maillard, M. P. Besse, Chem. Mater. 8 (1996) 1962. V. Prevot, C. P. Besse and F. Abraham, Inorg. Chem. 37 (1998) 4293. S. Therias, C. Mousty, C. P. Besse, Langmuir 12 (1996) 4914. U. Costantino, N. Coletti, M. G. Aloisi and F. Eliseï, Langmuir 15 (1999) 4454. J. Qiu and G. Villemure, J. Electroanal. Chem. 395 (1995) 159. F. Kooli, C. Depège, A. Ennaqadi, A. P.

33[Zn-Cr-SO4] phases (Figure 13) shows that the operating conditions can strongly modify the obtained LDH. 3Å” phase corresponding to severe dehydration at room temperature. All of these phases can be reversibly obtained. This points out that the washing and drying processes can be considered as post-synthesis treatments. 38 22 A. de Roy, C. P. -Schematic representation of polyoxometalate exchange via terephthalate compound in an LDH. 1 Å” phase in Figure 13 diagram corresponds to an irreversible transformation of the structure with no more rehydration or further anionic exchange capacity.

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Layered double hydroxides by ed.Vicente Rives.


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