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By Geoffrey Wilkinson

ISBN-10: 0080359507

ISBN-13: 9780080359502

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For the exchange to be reversible, a component must be present in the reservoir at the same chemical potential, p, that it has in the system. 10)to cover changes in the amounts in both phases of each of c components n,, . . dn. 11)has the form x dY where Y,like U, is an extensive thermodynamic function and x is a field? We need not ask what are the values of p, T,and p at the interface; indeed the question has no meaning within the description of the system now being used. 5. dn. 13) A third form of the fundamental equation will be useful when we come to discuss the statistical mechanics in Chapter 4.

Brush) pp. 220,375. University of California Press, Berkeley (1964). Addition to References Ref. 35 For a more accessible English translation. see van der Waals, J. D. On the continuiv of the gaseous and liquid srures (ed. with an Introductory Essay by J. S. Rowlinson) Srudies in Srurirricul Mechanics, Vol. 14. North-Holland, Amsterdam (1988). ndLinetietheory The cohesion of liquids and the concomitant tension in the gas-liquid surface are almost self-evident properties of liquids. We have seen in the last chapter how they can be explained in terms of forces between stationary molecules, and how this explanation can tell us something of the strength and range of these forces.

B. Nahcn 109, 375 (1922)and Bikerman, J. J. Arch. Hist. exact. Sci. This early period and the next thirty years were fully covered in a 22 MECHANICAL MOLECULAR MODELS review written by Challis (ref. 13) for the British Association. His review is the source on which the opening section of Maxwell's more accessible essay is based (ref. 14). Nineteenth century experiments and theories are discussed at length in the first threc chapters of Bakker, G. Kapillaritiit und Oberfliichenspannung. Vol. 6 of Handbuch der Fsperiinentalphysik (ed.

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Comprehensive coordination chemistry. Indexes by Geoffrey Wilkinson


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