Houses and Reactions of Thiazole (J. Metzger and E. Vincent).
normal artificial tools for Thiazole and Thiazolium Salts (G. Vernin).
Alkyl, Aryl, Aralkyl, and comparable Thiazole Derivatives (J. Aune et al.).
Thiazolecarboxylic Acids, Thiazolecarboxaldehydes, and Thiazolyl Ketones (R. Meyer).
Halo and Nitrothiazoles (L. Forlani and P. Todesco).
Chapter I homes and Reactions of Thiazole (pages 5–164): Jacques V. Metzger, Emile?Jean Vincent, Jacques Chouteau and Gilbert Mille
Chapter II basic artificial tools for Thiazole and Thiazolium Salts (pages 165–335): Gaston Vernin
Chapter III Alkyl, Aryl, Aralkyl, and similar Thiazole Derivatives (pages 337–518): Jean Pierre Aune, Henri Jean?Marie Dou and Jacqueline Crousier
Chapter IV Thiazolecarboxylic Acids, Thiazolecarboxaldehydes, and Thiazolyl Ketones (pages 519–563): Roger Meyer
Chapter V Halo? and Nitrothiazoles (pages 565–585): L. Forlani and P. E. Todesco
Read or Download Chemistry of Heterocyclic Compounds: Thiazole and Its Derivatives, Part One, Volume 34 PDF
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Extra resources for Chemistry of Heterocyclic Compounds: Thiazole and Its Derivatives, Part One, Volume 34
For these two compounds there is first a complete superposition of the bands corresponding to the second and third ionization potentials. 30e V for the second: it corresponds to the ionization of the lone pair of the amino group that is conjugated with the ring T system. 75 eV. 5 eV corresponding to the nitro group. All the assignments could be confirmed with good precision by CNDO/S calculations (Table 1-20). Bernardi et al. (131) have studied the halogen derivatives experimentally and theoretically.
086 160 123 TABLE 1-7. CALCULATED DIPOLE MOMENT OF THIAZOLJ? 61 dm Ref. 86 (116,158). 0 0, = +63" e, = -930 system - n) Fig. 1-5. Dipole moment of thiazole. 37 TABLE 1-8. DlPOLE MOMENTS CALCULATED FOR VARIOUS THIAZOLE DERIVATlVES Thiazolc derivatives Calcd (Debye) Ref. Measured (Debye) Ref. 75 146 146 146 146 146 146 146 146 146 146 146 146 146 116 - - Thiazole 2-Methyl 4-Methyl 5-Methyl 4-Amino 5-Amino 2-Chloro 4-Chloro 5-Chloro w" (T- 77 PPP PPP W* U - 77 ab initio HMO w" PPP W* 0'' PPP w* W1 PPP w* W* PPP W* PPP W* PPP W* PPP W* PPP PPP 38 - - - - - - I.
1-10 and Table 1-23).
Chemistry of Heterocyclic Compounds: Thiazole and Its Derivatives, Part One, Volume 34 by Metzger