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49] Konstantinov A O, Wahah Q, Nordell N, Lindefelt U (1997). Appl. Phys. Lett. 71: 90-92. 5772/2834 1. Introduction Polymers are macromolecules built up by the linking together, under formation of chemical bonds, of large numbers of much smaller molecules (monomers). Due to their structure they can be classified as linear, branched, or crosslinked polymers [1]. The dendritic topology (dendrimers, hyperbranched polymers) has recently been recognized as a new class of macromolecular architecture.

E. three in elementary monomer backbone), the absence of the C—O—C ether group in the case of BPDA-PDA allows increasing Td (defined at 10% wt. loss) of 48 °C in nitrogen and 100 °C in air in comparison to Td of PMDA-ODA (see Figure 7). Moreover, if the diamine ODA is replaced by PDA in BPDA-based PIs, Td increases of 68 °C in nitrogen and 105 °C in air. Indeed, this is due to the lower thermal stability of the ether bonds inducing earlier degradations than the rest of the structure [1,44]. 2. Thermal aging in inert atmosphere Figure 8 shows the evolution of the FTIR spectrum of BPDA-PDA before and after an aging at 300 °C in nitrogen during 1000 h and the evolution of the film thickness and the related breakdown field during this aging.

Polym. Sci. B Polym. Phys. 36: 1247. [38] Ito Y, Hikita M, Kimura T, Mizutani T (1990). Jpn. J. Appl. Phys. 29: 1128. [39] Ruggles-Wrenn M B, Broeckert J L (2009). J. Appl. Polym. Sci. 111: 228-236. [40] Schoeppner G A, Tandon G P, Ripberger E R (2007). Composites: Part A. 38: 890-904. [41] Tandon G P, Pochiraju K V, Schoeppner G A (2008). Mater. Sci. Eng. A. 498: 150-161. [42] Meador M A B, Johnston C J, Cavano P J, Frimer A A (1997). Macromolecules. 30: 32153223. [43] Meador M A B, Johnston C J, Frimer A A, Gilinsky-Sharon P (1999).

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Chemistry Explosives A Multiple Capability Sympathetic Detonator System For The U S Special Forces by James J. Chopack


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