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Carbon Quantum Dots: Synthesis, Properties and Applications - download pdf or read online

By Raz Jelinek

ISBN-10: 331943909X

ISBN-13: 9783319439099

ISBN-10: 3319439111

ISBN-13: 9783319439112

This booklet introduces a few of the elements of the rising box of carbon dots. Their structural and physico-chemical houses in addition to their present and destiny strength purposes are lined. a unique bankruptcy on graphene quantum dots is supplied. The reader also will locate diversified synthesis routes for carbon quantum dots.

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Additional resources for Carbon Quantum Dots: Synthesis, Properties and Applications

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24 involve several steps and appears somewhat elaborate, it enables one to fabricate uniform GQDs in large quantities. Furthermore, control of GQD 26 2 Carbon-Dot Synthesis Fig. 25 Template-directed synthesis of GQDs. Schemes showing the synthetic concept. a A trialkylphenyl residue (black) is attached to a graphene sheet (blue). Hydrogen atoms involved in stabilization of the GQDs are indicated in white; b molecular organization of a graphene nanoparticle stabilized by three trialkylphenyl residues; c a theoretical calculation depicting the GQD core (blue) enclosed by the alkyl chains.

A synthesis using phenylenediamine precursor and purification of Carbon-Dots exhibiting distinct colors by column chromatography; b colors of different Carbon-Dots fractions; c emission wavelengths; d hypothesized mechanism linking the emission colors to degree of surface oxidation. Reprinted with permission from Ding et al. [15]. Copyright (2016) American Chemical Society the same emission upon different excitations (Fig. 13b). The researchers hypothesized that in the small GQDs the fluorescence emission was ascribed to surface energy states, as the surface area is predominant compared to the crystalline core.

In parallel, holes were thermally generated upon the Carbon-Dots’ surface and the combined effect of electron injection and hole formation resulted in CL. While CL processes help to shed light upon Carbon-Dots’ photophysical properties, their practical applicability as a sensing tool has been limited due to the often complex redox reactions and their coupling to the Carbon-Dots, and the practical constrains of the technique in term of reaction yields and luminescence intensities. Fig. 19 Chemiluminescence (CL) in carbon-dots.

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Carbon Quantum Dots: Synthesis, Properties and Applications by Raz Jelinek


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