By W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)
Volume II/29 "Molecular Constants generally from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy" is deliberate to seem as a chain A, B, C and D1, D2, D3 for the diamagnetic, and E for the paramagnetic linear and polyatomic species, respectively. Like within the preseding volumes II/24 and II/19, that have seemed within the years round 1999 and 1992, respectively, the diamagnetic elements are prepared within the demeanour advised by way of Hill ("Hill's system", 1900), which means a virtually strict alphabetical order. The ionic species are integrated within the alphabetical association of the impartial ones in every one desk. the data is grouped in a different way compared to the former volumes. All suitable houses of a molecule and the corresponding parameters are available focused below its sum formulation in quantity II/29. this diminishes the necessity of turning pages simply because rotational and similar constants, dipole moments, limitations to inner rotation, hyperfine coupling parameters, or Zeeman info have been hitherto indexed in numerous tables. the current subvolume II/29D2 includes information for uneven most sensible molecules.
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Additional resources for Asymmetric Top Molecules. Part 2
The Theory of Electric and Magnetic Susceptibilities, Oxford, England: Oxford University Press, 1932. : Phys. Rev. 78 (1950) 699. : Phys. Rev. 85 (1952) 24. : Phys. Rev. 90 (1953) 303. : Nuclear Moments, New York: John Wiley & Sons, 1953. : Microwave Spectroscopy, New York: McGraw Hill Book Co, 1955. : Angular Momentum in Quantum Mechanics, Princeton: Princeton University Press, 1957. : J. Chem. Phys. 41 (1964) 793. : J. Chem. Phys. 40 (1964) 257. : Group Theory and Quantum Mechanics, New York: McGraw Hill Book Co, 1964.
24) The quantities in eqs. 22e) above are averages over the vibrational state in question. Vibrational ground-state data are normally evaluated in the rigid-rotor approximation. The error nk introduced thereby is considered to be less than 1% in the measured quantities. Thus, in computing Cgg el k para k and V gg in eqs. 22e) are the same from structural information and observing that Cgg dia k para k and V gg , from the but for a constant, one obtains the diamagnetic and paramagnetic shielding, V gg k k dia k and V gg .
J. Mol. Spectrosc. 86 (1981) 465. : Microwave Molecular Spectroscopy, New York: Wiley-Interscience, 1984. : J. Mol. Spectrosc. 163 (1994) 559. : J. Mol. Spectrosc. 251 (2008) 305. : J. Mol. , in press. 4 Electric dipole moments The molecular dipole moment in a vibrational state ȣ1, ȣ2, …, ȣ3Ní6 is determined by an analysis of the Stark effect of the rotational lines. If two or three components along the directions of the principal inertia axes exist, then at least two or three Stark components of different projection quantum number M of one line or at least two or three Stark components of different lines are needed for analysis.
Asymmetric Top Molecules. Part 2 by W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)