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Asymmetric Synthesis of Nitrogen Heterocycles by Jacques Royer, H. P. Husson PDF

By Jacques Royer, H. P. Husson

ISBN-10: 3527320369

ISBN-13: 9783527320363

Right here, all points of the subject are awarded in a compact demeanour. The publication is obviously established, and divided into sections -- uneven synthesis of heterocycles containing just one nitrogen and that of these with a couple of nitrogen as a heteroatom -- such that the required info might be came upon at a look. The foreign staff of authors offers vital experimental strategies, together with commercial applications.Essential for artificial chemists in pharmaceutical and agrochemical chemistry.

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1 Substituted Aziridines 29 a reactive substrate for a Staudinger-type reaction, leading to carbohydrate-fused aziridines [75]. H3CO O O S O H3CO OR NaN3 DMF O O N3 H3CO OR OH O OR H N (1) TsCl (2) PPh3 58% In general, the presence of an azido moiety vicinal to a good oxygenated leaving group is a sufficient requirement for the synthesis of aziridine rings via Staudinger-type mechanism. Recently, the preparation of polyfunctionalized azetidin-2-ones, bearing an aziridine ring and an hydroxyl moiety on the side chain, has been reported via aza-Payne displacement induced by triethylphosphine [76].

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Ed) (2006) Aziridines and Epoxides in Organic Synthesis, Wiley-VCH Verlag GmbH, Weinheim; (b) Osborn, H. M. I. and Sweeney, J. (1997) Tetrahedron: Asymmetry, 8, 1693–715; (c) Tanner, D. (1994) Angew. Chem. Int. Ed. , 33, 599–619; (d) Atkinson, R. S. (1999) Tetrahedron, 55, 1519–59; (e) Osborn, H. M. I. and Sweeney, J. (1997) Tetrahedron: Asymmetry, 8, 1693–715; (f) Kemp, J. G. (1991) Comprehensive Organic Synthesis (eds B. M. Trost and I. Fleming), Pergamon, Oxford, Vol. 5; (g) Watson, I. D. , Yu, L.

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Asymmetric Synthesis of Nitrogen Heterocycles by Jacques Royer, H. P. Husson

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