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Download e-book for kindle: Advances in Chemical Physics, Volume 19 by Ilya Prigogine

By Ilya Prigogine

ISBN-10: 0470143673

ISBN-13: 9780470143674

ISBN-10: 0471699241

ISBN-13: 9780471699248

The Advances in Chemical Physics sequence presents the chemical physics and actual chemistry fields with a discussion board for severe, authoritative reviews of advances in each quarter of the self-discipline. full of state of the art examine suggested in a cohesive demeanour no longer stumbled on in other places within the literature, every one quantity of the Advances in Chemical Physics sequence serves because the ideal complement to any complicated graduate classification dedicated to the examine of chemical physics.

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Extra info for Advances in Chemical Physics, Volume 19

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Glasstone, K. Laidler, and H. Eyring, The Theory of RafeProcesses, McGraw-Hill, New York, 1941. 32. C . C . Rankin, Thesis, University of Chicago, 1968. 33. C. C. Rankin and J. Light, J . Chem. Phys. 51, 1701 (1969). 34. S. Chan, J. Light, and J. Lin, J. Chem. r. 49, 86 (1968). 35. R. Gordon, J. Chem. Phys. 51, 14 (1969). 36. P. Pechukas and J. Light, J. Chem. Phys. 44, 3897 (1966). 37. R . E. Wyatt, J . Chem. Phys. 51, 3489 (1969). 38. R. N. Portcr and M. Karplus, J. Chem. Phys. 40, 1105 (1964).

Many of the problems of other workers arose from neglect of alternative reaction channels. (5) Simple systems offer the best approximation to the Langevin assumption of a point charge approaching a polarizable neutral molecule with a negligibly small “hard core” cross section. (6) Simple systems tend to have widely spaced energy IeveIs and few internal degrees of freedom. The partition functions of the reactants and of a loosely bound activated complex will therefore be very simple and of a form which validates the approximations made by Eyring, Hirschfelder and Taylor in their statistical calculation of the rates of ion-molecule reactions, and which they indeed carried out for the specific case of the Hi/H, reaction.

E. A. , and R. E. Wyatt, J . Chem. Phys. 51, 1253 (1969). Advances in Chemical Physics, Volume 19 Edited by I. Prigogine, Stuart A. Rice Copyright © 1971 by John Wiley & Sons, Inc. A REVIEW OF ION-MOLECULE REACTIONS* LEWIS FRIEDMAN AND BRYAN G. REUBEN? Department of Chemistry, Brookhaven National Laboratory, Upton, New York CONTENTS I. Introduction . . . 11. Historical Background . . . A. The Single Source Technique . . . . B. Further Development of the Single Source . . . C. The Development of the Tandem Mass Spectrometer .

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Advances in Chemical Physics, Volume 19 by Ilya Prigogine


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