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Advances in Catalysis, Vol. 7 by W.G. Frankenburg, V.I. Komarewsky, E.K. Rideal (Eds.) PDF

By W.G. Frankenburg, V.I. Komarewsky, E.K. Rideal (Eds.)

ISBN-10: 0120078074

ISBN-13: 9780120078073

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60 66 V. Electronic Properties of Nickel Oxide.. . . . . . . . . . . . . . . . VI. Carbon Monoxide Oxidation on Modified Nickel Oxide Catalysts. . . . . 68 VII. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 References. 72 Since in any catalytic reaction, at least one of the reactants must be chemisorbed, no theory of catalysis can be constructed before the mechanism of chemisorption on the surfaces under investigation is fully understood.

2962 (1952). 47. , Proc. Roy. A214, 413 (1952). 48. Dowden, D. , I n d . h'ng. Chem. 44, 977 (1952). 49. Dowden, D. A,, and Reynolds, P. No. 8, 184 (1950). 50. Reynolds, P. , J . Chem. p. 265 (1950). 51. , Trans. 42,689 (1946). 52. , J . Phys. & Colloid. Chem. 62, 1046 (1948). 53. No. 8, 166 (1950). 54. Stowe, R. , and Russell, W. , J . Am. Chem. Soc. 76, 319 (1954). 55. Wilson, A. , Proc. Roy. A133, 458 (1931); A134, 277 (1931). 56. , and Selwood, P. , J . Am. Chem. 74, 1750 (1952). 57. , and Selwood, P.

Above 550°C Cu20, NiO, COO CuO, MgO, CeOz, CaO A1203,ZnO, Fe203,TiOz, Cr203. It is of interest t o consider the semiconducting properties of these oxides. The first group are all p-type semiconductors. In the second group MgO, CuO, and CeOz are known t o be insulators below 550°C, whereas CuO is an intrinsic semiconductor. The third group consists of n-type semiconductors with the exception of Cr2O3, which very nearly has the properties of an intrinsic semiconductor, though it does show p-type conductivity.

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Advances in Catalysis, Vol. 7 by W.G. Frankenburg, V.I. Komarewsky, E.K. Rideal (Eds.)


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